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Basics of CHP
CHP technologies are conventional power generation systems with the means to make use of the energy remaining in exhaust gases, cooling systems, or other energy waste stream. Typical CHP prime movers include:
Combustion turbines
Gas turbines can be used in a variety of configurations:
(1) simple cycle operation which is a single gas turbine producing power only,
(2) combined heat and power (CHP) operation which is a simple cycle gas turbine with a heat recovery heat exchanger which recovers the heat in the turbine exhaust and converts it to useful thermal energy usually in the form of steam or hot water, and
(3) combined cycle operation in which high pressure steam is generated from recovered exhaust heat and used to create additional power using a steam turbine. Some combined cycles extract steam at an intermediate pressure for use in industrial processes and are combined cycle CHP systems.
Gas turbines are available in sizes ranging from 500 kilowatts (kW) to 250 megawatts (MW). The most efficient commercial technology for central station power-only generation is the gas turbine-steam turbine combined-cycle plant, with efficiencies approaching 60% LHV). Simple-cycle gas turbines for power-only generation are available with efficiencies approaching 40% (LHV). Gas turbines have long been used by utilities for peaking capacity. However, with changes in the power industry and advancements in the technology, the gas turbine is now being increasingly used for base-load power.
Gas turbines produce high-quality exhaust heat that can be used in CHP configurations to reach overall system efficiencies (electricity and useful thermal energy) of 70 to 80%. By the early 1980s, the efficiency and reliability of smaller gas turbines (1 to 40 MW) had progressed sufficiently to be an attractive choice for industrial and large institutional users for CHP applications.
Gas turbines are one of the cleanest means of generating electricity, with emissions of oxides of nitrogen (NOx) from some large turbines in the single-digit parts per million (ppm) range, either with catalytic exhaust cleanup or lean pre-mixed combustion. Because of their relatively high efficiency and reliance on natural gas as the primary fuel, gas turbines emit substantially less carbon dioxide (CO2) per kilowatt-hour (kWh) generated than any other fossil technology in general commercial use.
Reciprocating engines
Reciprocating internal combustion engines are a widespread and well-known technology. North American production exceeds 35 million units per year for automobiles, trucks, construction and mining equipment, marine propulsion, lawn care, and a diverse set of power generation applications. A variety of stationary engine products are available for a range of power generation market applications and duty cycles including standby and emergency power, peaking service, intermediate and baseload power, and combined heat and power (CHP). Reciprocating engines are available for power generation applications in sizes ranging from a few kilowatts to over 5 MW.
There are two basic types of reciprocating engines - spark ignition (SI) and compression ignition (CI). Spark ignition engines for power generation use natural gas as the preferred fuel, although they can be set up to run on propane, gasoline, or landfill gas. Compression ignition engines (often called diesel engines) operate on diesel fuel or heavy oil, or they can be set up to run in a dual-fuel configuration that burns primarily natural gas with a small amount of diesel pilot fuel.
Current generation natural gas engines offer low first cost, fast start-up, proven reliability when properly maintained, excellent load-following characteristics, and significant heat recovery potential. Electric efficiencies of natural gas engines range from 28% LHV for small stoichiometric engines (<100 kW) to over 40% LHV for large lean burn engines (> 3 MW). Waste heat recovered from the hot engine exhaust and from the engine cooling systems produces either hot water or low pressure steam for CHP applications. Overall CHP system efficiencies (electricity and useful thermal energy) of 70 to 80% are routinely achieved with natural gas engine systems.
The emissions signature of natural gas SI engines in particular has improved significantly in the last decade through better design and control of the combustion process and through the use of exhaust catalysts. Advanced lean burn natural gas engines are available that produce NOx levels as low as 50 ppmv @ 15% O2 (dry basis).
Boilers with steam turbines
Steam turbines are one of the most versatile and oldest prime mover technologies still in general production. Power generation using steam turbines has been in use for about 100 years, when they replaced reciprocating steam engines due to their higher efficiencies and lower costs. Conventional steam turbine power plants generate most of the electricity produced in the United States. The capacity of steam turbines can range from 50 kW to several hundred MWs for large utility power plants. Steam turbines are widely used for combined heat and power (CHP) applications.
Unlike gas turbine and reciprocating engine CHP systems where heat is a byproduct of power generation, steam turbines normally generate electricity as a byproduct of heat (steam) generation. A steam turbine is captive to a separate heat source and does not directly convert fuel to electric energy. The energy is transferred from the boiler to the turbine through high-pressure steam that in turn powers the turbine and generator. This separation of functions enables steam turbines to operate with an enormous variety of fuels, from natural gas to solid waste, including all types of coal, wood, wood waste, and agricultural byproducts (sugar cane bagasse, fruit pits, and rice hulls). In CHP applications, steam at lower pressure is extracted from the steam turbine and used directly or is converted to other forms of thermal energy.
Microturbines
Microturbines are small electricity generators that burn gaseous and liquid fuels to create high-speed rotation that turns an electrical generator. Today's microturbine technology is the result of development work in small stationary and automotive gas turbines, auxiliary power equipment, and turbochargers, much of which was pursued by the automotive industry beginning in the 1950s. Microturbines entered field testing around 1997 and began initial commercial service in 2000.
The size range for microturbines available and in development is from 30 to 350 kilowatts (kW), while conventional gas turbine sizes range from 500 kW to 250 megawatts (MW). Microturbines run at high speeds and, like larger gas turbines, can be used in power-only generation or in combined heat and power (CHP) systems. They are able to operate on a variety of fuels, including natural gas, sour gases (high sulfur, low Btu content), and liquid fuels such as gasoline, kerosene, and diesel fuel/distillate heating oil. In resource recovery applications, they burn waste gases that would otherwise be flared or released directly into the atmosphere.
Fuel Cells
The first working fuel cell was produced by Sir William Grove in 1842. The technology advanced slowly over the years but took a giant leap in the 1960s when General Electric produced the first practical fuel cell application for onboard electrical power for the Gemini and Apollo space capsules.
A fuel cell is an electrochemical energy conversion device that converts hydrogen and oxygen into electricity and heat. It is very much like a battery that can be recharged while power is drawn from it. Instead of recharging using electricity, however, a fuel cell uses hydrogen and oxygen.
A fuel cell consists of two electrodes, an anode and a cathode, separated by an electrolyte. Power is produced electrochemically when ions (charged particles) formed at one end of the electrodes with the aid of catalysts pass through the electrolyte. The current produced can be used for electricity.

Graphic from US Dept. of Energy
The major difference between most fuel cells is the type of electrolyte. Electrolyte types include phosphoric acid, molten carbonate, solid oxide, and proton exchange membrane.
Phosphoric Acid
Phosphoric acid fuel cells are generally considered "first generation" technology. These fuel cells operate at about 200°C (400°F) and achieve 40%-45% fuel-to-electricity efficiencies on a lower heating value (LHV) basis.
Molten Carbonate
Molten carbonate technology has the potential to reach fuel-to-electricity efficiencies of 50%-60% LHV. Operating temperatures for molten carbonate fuel cells (MCFCs) are around 650°C (1,200°F), which allows total system thermal efficiencies up to 85% LHV in combined-cycle applications. MCFCs have been operated on hydrogen, carbon monoxide, natural gas, propane, landfill gas, marine diesel, and simulated coal gasification products.
Solid Oxide
Solid oxide fuel cells (SOFCs) operate at temperatures up to 1,000°C (1,800°F), which further enhances combined-cycle performance. A solid oxide system usually uses a hard ceramic material instead of a liquid electrolyte. The solid-state ceramic construction enables the high temperatures, allows more flexibility in fuel choice, and contributes to stability and reliability. As with MCFCs, SOFCs are capable of fuel-to-electricity efficiencies of 50%-60% LHV and total system thermal efficiencies up to 85% LHV in combined-cycle applications.
Proton Exchange Membrane
These cells operate at relatively low temperatures (about 200°F), have high power density, can vary their output quickly to meet shifts in power demand, and are suited for applications in which quick start-up is required (e.g, transportation and power generation). The proton exchange membrane is a thin plastic sheet that allows hydrogen ions to pass through it. The membrane is coated on both sides with highly dispersed metal alloy particles (mostly platinum) that are active catalysts. As shown in the diagram above, hydrogen is fed to the anode side of the fuel cell, where the catalyst encourages the hydrogen atoms to release electrons and become hydrogen ions (protons). The electrons travel in the form of an electric current that can be used before it returns to the cathode side of the fuel cell, where oxygen has been fed. At the same time, the protons diffuse through the membrane to the cathode, where the hydrogen atom is recombined and reacted with oxygen to produce water, thus completing the overall process.
For more information, visit the DOE Fuel Cells Web site.
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